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Biological Nicotinamide Cofactor as a Redox-Active Motif for Reversible Electrochemical Energy Storage

Cited 12 time in Web of Science Cited 12 time in Scopus
Issue Date
2019-11
Citation
Angewandte Chemie - International Edition, Vol.58 No.47, pp.16764-16769
Keywords
bioenergeticscofactorsenergy storageorganic electrodesredox chemistry
Abstract
Nicotinamide adenine dinucleotide (NAD(+)) is one of the most well-known redox cofactors carrying electrons. Now, it is reported that the intrinsically charged NAD(+) motif can serve as an active electrode in electrochemical lithium cells. By anchoring the NAD(+) motif by the anion incorporation, redox activity of the NAD(+) is successfully implemented in conventional batteries, exhibiting the average voltage of 2.3 V. The operating voltage and capacity are tunable by altering the anchoring anion species without modifying the redox center itself. This work not only demonstrates the redox capability of NAD(+), but also suggests that anchoring the charged molecules with anion incorporation is a viable new approach to exploit various charged biological cofactors in rechargeable battery systems.
ISSN
1433-7851
URI
https://hdl.handle.net/10371/164957
DOI
https://doi.org/10.1002/anie.201906844
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Materials Science and Engineering (재료공학부)Journal Papers (저널논문_재료공학부)
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