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Preparation of LiCoPO4 and LiFePO4 coated LiCoPO4 materials with improved battery performance

Cited 63 time in Web of Science Cited 67 time in Scopus
Authors
Jang, Il-Chan; Lim, Hyunhe; Lee, Seungbyung; Karthikeyan, K.; Aravindan, V.; Kang, Kisuk; Yoon, Wonsub; Cho, Won Il; Lee, Yun-sung
Issue Date
2010-05
Citation
Journal of Alloys and Compounds, Vol.497 No.1-2, pp.321-324
Keywords
Lithium cobalt phosphateLithium ion phosphateSurface coatingSol-gel methodSolid-state reaction
Abstract
Olivine LiCoPO4 material has been successfully synthesized by solid-state reaction method without any carbon coating. The X-ray diffraction pattern shows that LiCoPO4 has a well developed orthorhombic structure with Prima space group The SEM analysis shows the particulate nature of the prepared materials with <200 nm size. The TEM analysis confirms that a 2-3 nm thick LiFePO4 layer is coated onto LiCoPO4. The LiFePO4 coated LiCoPO4 cell delivers a high initial discharge capacity of 132 mAhg(-1), which is 19 mAhg(-1) higher than the parent LiCoPO4 Furthermore, the LiFePO4 coated LiCoPO4 cell exhibits an improved capacity retention compared to the original LiCoPO4 during cycling Crown Copyright (C) 2010 Published by Elsevier B V. All rights reserved
ISSN
0925-8388
URI
https://hdl.handle.net/10371/165176
DOI
https://doi.org/10.1016/j.jallcom.2010.03.055
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Materials Science and Engineering (재료공학부)Journal Papers (저널논문_재료공학부)
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