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Asymmetric total synthesis of (+)-(3E)-pinnatifidenyne via abnormally regioselective Pd(0)-catalyzed endocyclization
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Hyun Su | - |
dc.contributor.author | Kim, Taewoo | - |
dc.contributor.author | Ahn, Jungmin | - |
dc.contributor.author | Yun, Hwayoung | - |
dc.contributor.author | Lim, Changjin | - |
dc.contributor.author | Jang, Jaebong | - |
dc.contributor.author | Sim, Jaehoon | - |
dc.contributor.author | An, Hongchan | - |
dc.contributor.author | Surh, Young-Joon | - |
dc.contributor.author | Lee, Jeeyeon | - |
dc.contributor.author | Suh, Young-Ger | - |
dc.date.accessioned | 2021-01-31T09:19:42Z | - |
dc.date.available | 2021-01-31T09:19:42Z | - |
dc.date.created | 2019-06-11 | - |
dc.date.created | 2019-06-11 | - |
dc.date.issued | 2018-02 | - |
dc.identifier.citation | Journal of Organic Chemistry, Vol.83 No.4, pp.1997-2005 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.other | 75159 | - |
dc.identifier.uri | https://hdl.handle.net/10371/172574 | - |
dc.description.abstract | The asymmetric total synthesis of the marine natural product (+)-(3E)-pinnatifidenyne was accomplished. The key features of the synthesis involve the construction of an eight membered cyclic ether by the abnormally regioselective Pd(0)-catalyzed cyclization, the installation of a double bond in the oxocene skeleton by sequential in situ deconjugative isomerization, and the efficient introduction of the crucial chloride mediated by the substrate-controlled diastereoselective reduction. | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Asymmetric total synthesis of (+)-(3E)-pinnatifidenyne via abnormally regioselective Pd(0)-catalyzed endocyclization | - |
dc.type | Article | - |
dc.contributor.AlternativeAuthor | 서영준 | - |
dc.identifier.doi | 10.1021/acs.joc.7b02937 | - |
dc.citation.journaltitle | Journal of Organic Chemistry | - |
dc.identifier.wosid | 000427094200033 | - |
dc.identifier.scopusid | 2-s2.0-85042202629 | - |
dc.citation.endpage | 2005 | - |
dc.citation.number | 4 | - |
dc.citation.startpage | 1997 | - |
dc.citation.volume | 83 | - |
dc.identifier.sci | 000427094200033 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Surh, Young-Joon | - |
dc.contributor.affiliatedAuthor | Lee, Jeeyeon | - |
dc.contributor.affiliatedAuthor | Suh, Young-Ger | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | ALLYLIC ALKYLATION | - |
dc.subject.keywordPlus | DOUBLE-BOND | - |
dc.subject.keywordPlus | ISOMERIZATION | - |
dc.subject.keywordPlus | CONSTRUCTION | - |
dc.subject.keywordPlus | CYCLIZATION | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | ALCOHOLS | - |
dc.subject.keywordPlus | SKELETON | - |
dc.subject.keywordPlus | CONCISE | - |
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