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Construction of the azacyclic core of tabernaemontanine-related alkaloids via tandem reformatsky aza-claisen rearrangement
Cited 9 time in
Web of Science
Cited 9 time in Scopus
- Authors
- Issue Date
- 2017-02
- Publisher
- American Chemical Society
- Citation
- Journal of Organic Chemistry, Vol.82 No.3, pp.1464-1470
- Abstract
- A divergent synthetic methodology for a tabernaemontanine-related alkaloid was developed. The synthetic route features practical improvements in the Pictet-Spengler cyclization for the tetrahydro-fi-carboline intermediate and an unprecedented tandem Reformatsky aza-Claisen rearrangement to create the core carbon skeleton and stereochemistries of tabernaemontanine-related alkaloids.
- ISSN
- 0022-3263
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