Publications
Detailed Information
New Insight into Microstructure Engineering of Ni-Rich Layered Oxide Cathode for High Performance Lithium Ion Batteries
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jung, Chul-Ho | - |
dc.contributor.author | Kim, Do-Hoon | - |
dc.contributor.author | Eum, Donggun | - |
dc.contributor.author | Kim, Kyeong-Ho | - |
dc.contributor.author | Choi, Jonghyun | - |
dc.contributor.author | Lee, Jongwon | - |
dc.contributor.author | Kim, Hyung-Ho | - |
dc.contributor.author | Kang, Kisuk | - |
dc.contributor.author | Hong, Seong-Hyeon | - |
dc.date.accessioned | 2022-04-20T07:16:53Z | - |
dc.date.available | 2022-04-20T07:16:53Z | - |
dc.date.created | 2021-07-07 | - |
dc.date.created | 2021-07-07 | - |
dc.date.created | 2021-07-07 | - |
dc.date.issued | 2021-05 | - |
dc.identifier.citation | Advanced Functional Materials, Vol.31 No.18, p. 2010095 | - |
dc.identifier.issn | 1616-301X | - |
dc.identifier.other | 137323 | - |
dc.identifier.uri | https://hdl.handle.net/10371/178474 | - |
dc.description.abstract | Ni-rich layered LiNixCoyMn1-x-yO2 (LNCM) with Ni content over >90% is considered as a promising lithium ion battery (LIB) cathode, attributed by its low cost and high practical capacity. However, Ni-rich LNCM inevitably suffers rapid capacity fading at a high state of charge due to the mechanochemical breakdown; in particular, the microcrack formation has been regarded as one of the main culprits for Ni-rich layered cathode failure. To address these issues, Ni-rich layered cathodes with a textured microstructure are developed by phosphorous and boron doping. Attributed by the textured morphology, both phosphorous- and boron-doped cathodes suppress microcrack formation and show enhanced cycle stability compared to the undoped cathode. However, there exists a meaningful capacity retention difference between the doped cathodes. By adapting the various analysis techniques, it is shown that the boron-doped Ni-rich layered cathode displays better cycle stability not only by its ability to suppress microcracks during cycling but also by its primary particle morphology that is reluctant to oxygen evolution. The present work reveals that not only restraint of particle cracks but also suppression of oxygen release by developing the oxygen stable facets is important for further improvements in state-of-the-art Li ion battery Ni-rich layered cathode materials. | - |
dc.language | 영어 | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.title | New Insight into Microstructure Engineering of Ni-Rich Layered Oxide Cathode for High Performance Lithium Ion Batteries | - |
dc.type | Article | - |
dc.contributor.AlternativeAuthor | 강기석 | - |
dc.identifier.doi | 10.1002/adfm.202010095 | - |
dc.citation.journaltitle | Advanced Functional Materials | - |
dc.identifier.wosid | 000621913500001 | - |
dc.identifier.scopusid | 2-s2.0-85101626595 | - |
dc.citation.number | 18 | - |
dc.citation.startpage | 2010095 | - |
dc.citation.volume | 31 | - |
dc.identifier.sci | 000621913500001 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Kang, Kisuk | - |
dc.contributor.affiliatedAuthor | Hong, Seong-Hyeon | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | THERMAL-INSTABILITY | - |
dc.subject.keywordPlus | OXYGEN VACANCIES | - |
dc.subject.keywordPlus | BULK LATTICE | - |
dc.subject.keywordPlus | LI | - |
dc.subject.keywordPlus | SURFACE | - |
dc.subject.keywordPlus | BORON | - |
dc.subject.keywordPlus | TRANSITION | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordPlus | EVOLUTION | - |
dc.subject.keywordAuthor | boron doping | - |
dc.subject.keywordAuthor | lithium ion batteries | - |
dc.subject.keywordAuthor | morphology control | - |
dc.subject.keywordAuthor | Ni& | - |
dc.subject.keywordAuthor | #8208 | - |
dc.subject.keywordAuthor | rich layered oxide | - |
dc.subject.keywordAuthor | oxygen evolution | - |
- Appears in Collections:
- Files in This Item:
- There are no files associated with this item.
Item View & Download Count
Items in S-Space are protected by copyright, with all rights reserved, unless otherwise indicated.