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Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism

Cited 5 time in Web of Science Cited 6 time in Scopus
Authors

Kim, Dasom; Yoo, Haneul; Kim, Kyunghwan; Kim, Dongwook; Kim, Ki Tae; Kim, Cheoljae; Kim, Jin Yeong; Moon, Hoi Ri; Kim, Min

Issue Date
2022-05
Publisher
Royal Society of Chemistry
Citation
Chemical Communications, Vol.58 No.40, pp.5948-5951
Abstract
A covalent connection between two orthogonal functional groups (-NH2 and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.
ISSN
1359-7345
URI
https://hdl.handle.net/10371/182742
DOI
https://doi.org/10.1039/d2cc01031c
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  • College of Education
  • Department of Chemistry Education
Research Area Coordination Chemistry, Metal-Organic Frameworks, Porous Materials and Composites

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