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Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism
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Cited 5 time in Scopus
- Authors
- Issue Date
- 2022-05
- Publisher
- Royal Society of Chemistry
- Citation
- Chemical Communications, Vol.58 No.40, pp.5948-5951
- Abstract
- A covalent connection between two orthogonal functional groups (-NH2 and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.
- ISSN
- 1359-7345
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