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Interplay between oxygen defects and dopants: Effect on structure and performance of HfO2-based ferroelectrics

Cited 61 time in Web of Science Cited 61 time in Scopus
Authors

Materano, M.; Lomenzo, P.D.; Kersch, A.; Park, M.H.; Mikolajick, T.; Schroeder, U.

Issue Date
2021-05
Publisher
Royal Society of Chemistry
Citation
Inorganic Chemistry Frontiers, Vol.8 No.10, pp.2650-2672
Abstract
Ten years after the first report on ferroelectricity in HfO2, researchers are still occupied unraveling the different causes behind this phenomenon. Among them, oxygen related defects seem to play a major role, affecting both crystalline phase formation and performance of HfO2-based devices. This review surveys the available literature and provides a broad picture on the topic, starting with an overview of existing oxygen-related defects, assessing the extensive calculations and experimental reports on phase stabilization in both undoped and doped HfO2 and concluding with a discussion of device reliability involving oxygen vacancies, first in more classical HfO2 applications such as MOSFET high-k metal gate and resistive switching devices and later in the three major groups of ferroelectric non-volatile memory devices. © the Partner Organisations.
ISSN
2052-1553
URI
https://hdl.handle.net/10371/183858
DOI
https://doi.org/10.1039/d1qi00167a
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