A theoretical framework for oxygen redox chemistry for sustainable batteries

Cited 13 time in Web of Science Cited 14 time in Scopus

Kim, Byunghoon; Song, Jun-Hyuk; Eum, Donggun; Yu, Seungju; Oh, Kyungbae; Lee, Myeong Hwan; Jang, Ho-Young; Kang, Kisuk

Issue Date
Nature Sustainability, Vol.5 No.8, pp.708-716
Lithium-rich layered oxides have emerged as a new model for designing the next generation of cathode materials for batteries to assist the transition to a greener energy system. The unique oxygen redox mechanism of such cathodes enables extra energy storage capacity beyond the contribution from merely transition metal ions; however, their practical application is hindered by the destabilizing structural changes during operation. Here we present a theoretical framework for the triptych of structural disorder, bond covalency and oxygen redox chemistry that applies to a wide range of layered oxides. It is revealed that structural disorder stabilizes the oxygen redox by promoting the formation of oxygen covalent bonds in favour of electrochemical reversibility. Oxygen dimers are found to move freely within the lattice structure and serve as a key catalyst of the poor structural resilience. Such fundamental understanding provides fresh insights that could inform strategies to mitigate the limitations of anionic redox cathodes, moving us a step closer to tapping into their enormous potential. Anionic redox has emerged as a new frontier in the design of high-energy cathode materials for next-generation batteries. This study provides a theoretical framework to understand the trilateral correlation of oxygen redox, structural disorder and bond covalency.
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Materials Science and Engineering (재료공학부)Journal Papers (저널논문_재료공학부)
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