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Ruthenium-Catalyzed Redox-Neutral and Single-Step Amide Synthesis from Alcohol and Nitrile with Complete Atom Economy
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kang, Byungjoon | - |
dc.contributor.author | Fu, Zhenqian | - |
dc.contributor.author | Hong, Soon Hyeok | - |
dc.date.accessioned | 2023-04-19T07:11:29Z | - |
dc.date.available | 2023-04-19T07:11:29Z | - |
dc.date.created | 2021-05-20 | - |
dc.date.issued | 2013-08 | - |
dc.identifier.citation | Journal of the American Chemical Society, Vol.135 No.32, pp.11704-11707 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://hdl.handle.net/10371/190856 | - |
dc.description.abstract | A completely atom-economical and redox-neutral catalytic amide synthesis from an alcohol and a nitrite is realized. The amide C-N bond is efficiently formed between the nitrogen atom of nitrile and the alpha-carbon of alcohol, with the help of an N-heterocyclic carbene-based ruthenium catalyst, without a single by-product. A utility of the reaction was demonstrated by synthesizing C-13 or N-15 isotope-labeled amides without involvement of any separate reduction and oxidation step. | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Ruthenium-Catalyzed Redox-Neutral and Single-Step Amide Synthesis from Alcohol and Nitrile with Complete Atom Economy | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ja404695t | - |
dc.citation.journaltitle | Journal of the American Chemical Society | - |
dc.identifier.wosid | 000323241200007 | - |
dc.identifier.scopusid | 2-s2.0-84882237881 | - |
dc.citation.endpage | 11707 | - |
dc.citation.number | 32 | - |
dc.citation.startpage | 11704 | - |
dc.citation.volume | 135 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Hong, Soon Hyeok | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | STABLE-ISOTOPES | - |
dc.subject.keywordPlus | BOND FORMATION | - |
dc.subject.keywordPlus | HYDRIDE COMPLEXES | - |
dc.subject.keywordPlus | HETERONUCLEAR NMR | - |
dc.subject.keywordPlus | COUPLING REAGENTS | - |
dc.subject.keywordPlus | LARGER PROTEINS | - |
dc.subject.keywordPlus | PRIMARY AMINES | - |
dc.subject.keywordPlus | IMINES | - |
dc.subject.keywordPlus | HYDROGENATION | - |
dc.subject.keywordPlus | AMIDATION | - |
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