Publications
Detailed Information
Chemoselective Primary Amination of Aryl Boronic Acids by PIII/PV═O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO : Chemoselective Primary Amination of Aryl Boronic Acids by P-III/P-V=O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hong, Seung Youn | - |
dc.contributor.author | Radosevich, Alexander T. | - |
dc.date.accessioned | 2023-05-03T07:46:26Z | - |
dc.date.available | 2023-05-03T07:46:26Z | - |
dc.date.created | 2023-05-02 | - |
dc.date.created | 2023-05-02 | - |
dc.date.issued | 2022-05 | - |
dc.identifier.citation | Journal of the American Chemical Society, Vol.144 No.20, pp.8902-8907 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://hdl.handle.net/10371/191831 | - |
dc.description.abstract | A catalytic approach to intercept the transient HNO for a chemoselective primary amination of arylboronic acids isreported. A phosphetane-based catalyst operating within PIII/PV???O redox cycling is shown to capture HNO, generated in situ byNef decomposition of 2-nitropropane, to selectively install the primary amino group at aryl Csp2centers. The method furnishesversatile primary arylamines from arylboronic acid substrates with the preservation of otherwise reactive functional groups | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Chemoselective Primary Amination of Aryl Boronic Acids by PIII/PV═O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO | - |
dc.title.alternative | Chemoselective Primary Amination of Aryl Boronic Acids by P-III/P-V=O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/jacs.2c02922 | - |
dc.citation.journaltitle | Journal of the American Chemical Society | - |
dc.identifier.wosid | 000805981500005 | - |
dc.identifier.scopusid | 2-s2.0-85131018318 | - |
dc.citation.endpage | 8907 | - |
dc.citation.number | 20 | - |
dc.citation.startpage | 8902 | - |
dc.citation.volume | 144 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Hong, Seung Youn | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | AMMONIA EQUIVALENT | - |
dc.subject.keywordPlus | PRIMARY ANILINES | - |
dc.subject.keywordPlus | NITROXYL HNO | - |
dc.subject.keywordPlus | HALIDES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | CHLORIDES | - |
dc.subject.keywordPlus | AMINES | - |
dc.subject.keywordPlus | ALKYL | - |
- Appears in Collections:
- Files in This Item:
- There are no files associated with this item.
Item View & Download Count
Items in S-Space are protected by copyright, with all rights reserved, unless otherwise indicated.