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Synthetic Utility of N-Benzoyloxyamides as an Alternative Precursor of Acylnitrenoids for γ-Lactam Formation : Synthetic Utility of N-Benzoyloxyamides as an Alternative Precursor of Acylnitrenoids for gamma-Lactam Formation
DC Field | Value | Language |
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dc.contributor.author | Huh, Soohee | - |
dc.contributor.author | Hong, Seung Youn | - |
dc.contributor.author | Chang, Sukbok | - |
dc.date.accessioned | 2023-05-03T07:46:44Z | - |
dc.date.available | 2023-05-03T07:46:44Z | - |
dc.date.created | 2023-05-02 | - |
dc.date.created | 2023-05-02 | - |
dc.date.issued | 2019-04 | - |
dc.identifier.citation | Organic Letters, Vol.21 No.8, pp.2808-2812 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://hdl.handle.net/10371/191838 | - |
dc.description.abstract | Described herein is the development of a new entry of acylnitrenoid precursors for gamma-lactam synthesis via an intramolecular C-H amidation reaction. Upon Ir catalysis, N-benzoyloxyamides serve as efficient substrates to afford 5-membered amides. Mechanistic studies revealed that the generation of a putative Ir-carbonylnitrenoid via N-O bond cleavage is facilitated by the chelation of countercations. This protocol offers a convenient and step-economic route to gamma-lactams starting from the corresponding carboxylic acids. | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Synthetic Utility of N-Benzoyloxyamides as an Alternative Precursor of Acylnitrenoids for γ-Lactam Formation | - |
dc.title.alternative | Synthetic Utility of N-Benzoyloxyamides as an Alternative Precursor of Acylnitrenoids for gamma-Lactam Formation | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.orglett.9b00791 | - |
dc.citation.journaltitle | Organic Letters | - |
dc.identifier.wosid | 000465644300067 | - |
dc.identifier.scopusid | 2-s2.0-85064112448 | - |
dc.citation.endpage | 2812 | - |
dc.citation.number | 8 | - |
dc.citation.startpage | 2808 | - |
dc.citation.volume | 21 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Hong, Seung Youn | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | C-H AMIDATION | - |
dc.subject.keywordPlus | PROTECTED AMINES | - |
dc.subject.keywordPlus | AMINATION | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | MILD | - |
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