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Ir(III)-Catalyzed Stereoselective Haloamidation of Alkynes Enabled by Ligand Participation
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hong, Seung Youn | - |
dc.contributor.author | Son, Junsoo | - |
dc.contributor.author | Kim, Dongwook | - |
dc.contributor.author | Chang, Sukbok | - |
dc.date.accessioned | 2023-05-03T07:46:47Z | - |
dc.date.available | 2023-05-03T07:46:47Z | - |
dc.date.created | 2023-05-02 | - |
dc.date.created | 2023-05-02 | - |
dc.date.issued | 2018-10 | - |
dc.identifier.citation | Journal of the American Chemical Society, Vol.140 No.39, pp.12359-12363 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://hdl.handle.net/10371/191839 | - |
dc.description.abstract | Described herein is the application of a strategy of ligand participation for the Ir-catalyzed imido transfer into alkynes. On the basis of a stoichiometric [3 + 2] cycloaddition of Cp*Ir(III)(kappa(2)-N,O-chelate) with alkynyl dioxazolone, a catalytic haloamidation was developed for the first time by employing [Cp*IrCl2](2) precatalyst and NaX salts (X = Cl or Br) as practical halide sources to furnish synthetically versatile Z-(halovinyl)lactams with excellent stereoselectivity. | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Ir(III)-Catalyzed Stereoselective Haloamidation of Alkynes Enabled by Ligand Participation | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/jacs.8b08134 | - |
dc.citation.journaltitle | Journal of the American Chemical Society | - |
dc.identifier.wosid | 000446920100012 | - |
dc.identifier.scopusid | 2-s2.0-85053848161 | - |
dc.citation.endpage | 12363 | - |
dc.citation.number | 39 | - |
dc.citation.startpage | 12359 | - |
dc.citation.volume | 140 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Hong, Seung Youn | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | C-H AMIDATION | - |
dc.subject.keywordPlus | COUPLING REACTIONS | - |
dc.subject.keywordPlus | CASCADE REACTIONS | - |
dc.subject.keywordPlus | AMIDO TRANSFER | - |
dc.subject.keywordPlus | MILD | - |
dc.subject.keywordPlus | AMINATION | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | DIOXAZOLONES | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | AMINES | - |
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