Publications
Detailed Information
[4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the Cp Ligand : [4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the CpLigand
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hong, Seung Youn | - |
dc.contributor.author | Jeong, Jisu | - |
dc.contributor.author | Chang, Sukbok | - |
dc.date.accessioned | 2023-05-03T07:46:52Z | - |
dc.date.available | 2023-05-03T07:46:52Z | - |
dc.date.created | 2023-05-02 | - |
dc.date.created | 2023-05-02 | - |
dc.date.issued | 2017-02 | - |
dc.identifier.citation | Angewandte Chemie International Edition, Vol.56 No.9, pp.2408-2412 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://hdl.handle.net/10371/191841 | - |
dc.description.abstract | A change in reaction pathway was achieved for the first time by tuning the cyclopentadienyl (Cp) ligand used for the rhodium-catalyzed cyclization of benzamides with conjugated enynones. Depending on the Cp ligand, the reaction pathway switched between [4+2] and [4+1] annulation. Electronic effects turned out to be crucial for the product distribution. The dichotomy was attributed to the alteration of the Lewis acidity of the resultant Cp-bound rhodium species. | - |
dc.language | 영어 | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.title | [4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the Cp Ligand | - |
dc.title.alternative | [4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the CpLigand | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/anie.201612559 | - |
dc.citation.journaltitle | Angewandte Chemie International Edition | - |
dc.identifier.wosid | 000395566600029 | - |
dc.identifier.scopusid | 2-s2.0-85010425283 | - |
dc.citation.endpage | 2412 | - |
dc.citation.number | 9 | - |
dc.citation.startpage | 2408 | - |
dc.citation.volume | 56 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Hong, Seung Youn | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | C-H ACTIVATION | - |
dc.subject.keywordPlus | N BOND FORMATION | - |
dc.subject.keywordPlus | FACILE SYNTHESIS | - |
dc.subject.keywordPlus | DIAZO-COMPOUNDS | - |
dc.subject.keywordPlus | ALKENES | - |
dc.subject.keywordPlus | KETONES | - |
dc.subject.keywordPlus | CYCLOPROPANATION | - |
dc.subject.keywordPlus | DONOR/ACCEPTOR | - |
dc.subject.keywordPlus | SELECTIVITY | - |
dc.subject.keywordPlus | BENZAMIDES | - |
dc.subject.keywordAuthor | annulations | - |
dc.subject.keywordAuthor | cyclopentadienyl ligands | - |
dc.subject.keywordAuthor | reaction mechanisms | - |
dc.subject.keywordAuthor | rhodium catalysis | - |
- Appears in Collections:
- Files in This Item:
- There are no files associated with this item.
Item View & Download Count
Items in S-Space are protected by copyright, with all rights reserved, unless otherwise indicated.