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Rhodium-catalyzed selective C–H functionalization of NNN tridentate chelating compounds via a rollover pathway : Rhodium-catalyzed selective C-H functionalization of NNN tridentate chelating compounds via a rollover pathway

Cited 28 time in Web of Science Cited 30 time in Scopus
Authors

Hong, Seung Youn; Kwak, Jaesung; Chang, Sukbok

Issue Date
2016-01
Publisher
Royal Society of Chemistry
Citation
Chemical Communications, Vol.52 No.15, pp.3159-3162
Abstract
Reported herein is the first example of the Rh(NHC)-catalyzed selective bis C-H alkylation of NNN tridentate chelating compounds in reaction with alkenes. The observed excellent site-selectivity can readily be explained by the postulated rollover pathway in the C-H bond activation step. The reaction is highly facile affording bis-alkylated tridentate products in high yields over a broad range of versatile heteroarene substrates and alkene reactants including ethylene gas, thus enabling its applications to be feasible in coordination and synthetic chemistry.
ISSN
1359-7345
URI
https://hdl.handle.net/10371/191842
DOI
https://doi.org/10.1039/c5cc09960a
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  • College of Natural Sciences
  • Department of Chemistry
Research Area Computational Modeling, Inorganic Chemistry, Molecular Catalysis, Organic Synthesis

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