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Rhodium-catalyzed selective C–H functionalization of NNN tridentate chelating compounds via a rollover pathway : Rhodium-catalyzed selective C-H functionalization of NNN tridentate chelating compounds via a rollover pathway
Cited 28 time in
Web of Science
Cited 30 time in Scopus
- Authors
- Issue Date
- 2016-01
- Publisher
- Royal Society of Chemistry
- Citation
- Chemical Communications, Vol.52 No.15, pp.3159-3162
- Abstract
- Reported herein is the first example of the Rh(NHC)-catalyzed selective bis C-H alkylation of NNN tridentate chelating compounds in reaction with alkenes. The observed excellent site-selectivity can readily be explained by the postulated rollover pathway in the C-H bond activation step. The reaction is highly facile affording bis-alkylated tridentate products in high yields over a broad range of versatile heteroarene substrates and alkene reactants including ethylene gas, thus enabling its applications to be feasible in coordination and synthetic chemistry.
- ISSN
- 1359-7345
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