Publications
Detailed Information
Ultra-pH-Sensitive Small Molecule Probe Showing a Ratiometric Fluorescence Color Change
Cited 9 time in
Web of Science
Cited 8 time in Scopus
- Authors
- Issue Date
- 2020-06
- Publisher
- WILEY-V C H VERLAG GMBH
- Citation
- Chemphotochem, Vol.4 No.6, pp.393-397
- Abstract
- We synthesized an amphiphilic small molecule 1 by attaching oligo(ethylene glycol) (OEG) and N,N-diethylamine (DEA) units to a fluorescent dicyanodistyrylbenzene (DCS) core. The molecule is fully soluble in aqueous solution at low pH (pH<4.3) by protonation of the DEA groups; but, above pH 4.3, it self-assembles to form nanoparticles due to increased hydrophobicity upon deprotonation, leading to a ratiometric fluorescence color change from green emission in the monomeric form (lambda(em,max)=538 nm) to red emission in the aggregated form (lambda(em,max)=646 nm). It should be noted that the ratio of emission intensities at 538 nm and 646 nm (R=I-538/I-646) changes drastically about 42-fold within a very narrow pH range of 4.3-4.6.
- ISSN
- 2367-0932
- Files in This Item:
- There are no files associated with this item.
Item View & Download Count
Items in S-Space are protected by copyright, with all rights reserved, unless otherwise indicated.