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Ambipolar Memristive Phenomenon in Large-Scale, Few-Layered alpha MoO3 Recrystallized Films
Cited 5 time in
Web of Science
Cited 7 time in Scopus
- Authors
- Issue Date
- 2019-01
- Publisher
- John Wiley and Sons Ltd
- Citation
- Advanced Materials Interfaces, Vol.6 No.2, p. 1801591
- Abstract
- Studies of two-dimensional (2D) oxide materials are not common, primarily because of the difficulty in obtaining crystal sizes large enough to fabricate devices structures from exfoliation of bulk crystals. Among the layered oxide materials, alpha molybdenum trioxide (alpha MoO3) is of particular interest because of its wide bandgap and high hole mobility. Here the growth of highly uniform, large-scale, ambipolar, few-layered alpha MoO3 that is appropriate for nanofabrication is reported. Crystal grain sizes on the order of 5 mu m are observed across samples as large as 10 x 10 mm(2) with hexagonal grain boundaries and surface roughness of less than 500 pm rms. Exact [010] crystal orientation, characteristic of the layered atomic structure alpha MoO3, is observed. The measured bandgap energy is approximate to 2.8 eV. Carrier mobilities in polycrystalline films are and 2.28 cm(2) V-1 s(-1) (hole) and 3.18 cm(2) V-1 s(-1) (electron) at room temperature in air. Simple field-effect device structures are characterized by ambipolar carrier transport producing memristive device characteristics, which is attributed to a polarization field produced by the strong coupling between electron and phonons in these crystals.
- ISSN
- 2196-7350
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