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Enantioselective Synthesis of Chiral α-Alkylthiomalonates via a Phase-Transfer-Catalyzed α-Sulfenylation of α-Alkylmalonates : Enantioselective Synthesis of Chiral alpha-Alkylthiomalonates via a Phase-Transfer-Catalyzed alpha-Sulfenylation of alpha-Alkylmalonates
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Jung, So Hyun | - |
| dc.contributor.author | Kim, Byungsoo | - |
| dc.contributor.author | Park, Cheonhyoung | - |
| dc.contributor.author | Kim, Jeongseok | - |
| dc.contributor.author | Ha, Min Woo | - |
| dc.contributor.author | Hong, Suckchang | - |
| dc.contributor.author | Park, Hyeung-geun | - |
| dc.date.accessioned | 2023-12-11T01:16:08Z | - |
| dc.date.available | 2023-12-11T01:16:08Z | - |
| dc.date.created | 2019-11-13 | - |
| dc.date.created | 2019-11-13 | - |
| dc.date.created | 2019-11-13 | - |
| dc.date.created | 2019-11-13 | - |
| dc.date.issued | 2019-09 | - |
| dc.identifier.citation | Asian Journal of Organic Chemistry, Vol.8 No.9, pp.1732-1739 | - |
| dc.identifier.issn | 2193-5807 | - |
| dc.identifier.uri | https://hdl.handle.net/10371/197977 | - |
| dc.description.abstract | A synthetic method for accessing chiral alpha-alkylthio-alpha-alkylmalonates was successfully established. The enantioselective alpha-sulfenylation of alpha-alkylmalonates via phase-transfer catalysis [N-alkylthiophthalimide, 50% aq. KOH, toluene, -40 degrees C and N-2 ',3 ',4 '-trifluorophenyl-dihydroquinidium bromide] provided the corresponding alpha-alkylthio-alpha-alkylmalonates in high chemical yields (up to 97%) and optical purities (up to 90% ee). | - |
| dc.language | 영어 | - |
| dc.publisher | Wiley - VCH Verlag GmbH & Co. KG | - |
| dc.title | Enantioselective Synthesis of Chiral α-Alkylthiomalonates via a Phase-Transfer-Catalyzed α-Sulfenylation of α-Alkylmalonates | - |
| dc.title.alternative | Enantioselective Synthesis of Chiral alpha-Alkylthiomalonates via a Phase-Transfer-Catalyzed alpha-Sulfenylation of alpha-Alkylmalonates | - |
| dc.type | Article | - |
| dc.identifier.doi | 10.1002/ajoc.201900346 | - |
| dc.citation.journaltitle | Asian Journal of Organic Chemistry | - |
| dc.identifier.wosid | 000482533600001 | - |
| dc.identifier.scopusid | 2-s2.0-85071268714 | - |
| dc.citation.endpage | 1739 | - |
| dc.citation.number | 9 | - |
| dc.citation.startpage | 1732 | - |
| dc.citation.volume | 8 | - |
| dc.description.isOpenAccess | N | - |
| dc.contributor.affiliatedAuthor | Hong, Suckchang | - |
| dc.contributor.affiliatedAuthor | Park, Hyeung-geun | - |
| dc.type.docType | Article | - |
| dc.description.journalClass | 1 | - |
| dc.subject.keywordPlus | PRACTICAL ASYMMETRIC-SYNTHESIS | - |
| dc.subject.keywordPlus | ALKYLATION | - |
| dc.subject.keywordPlus | AMINO | - |
| dc.subject.keywordPlus | ACIDS | - |
| dc.subject.keywordPlus | SULFOXIDES | - |
| dc.subject.keywordPlus | SULFIDES | - |
| dc.subject.keywordPlus | DESIGN | - |
| dc.subject.keywordPlus | THIOLS | - |
| dc.subject.keywordAuthor | asymmetric synthesis | - |
| dc.subject.keywordAuthor | enantioselectivity | - |
| dc.subject.keywordAuthor | phase-transfer catalysis | - |
| dc.subject.keywordAuthor | alpha-sulfenylation | - |
| dc.subject.keywordAuthor | alpha-thiomalonates | - |
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