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Hydrogen Storage in a Potassium-Ion-Bound Metal-Organic Framework Incorporating Crown Ether Struts as Specific Cation Binding Sites
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lim, Dae-Woon | - |
dc.contributor.author | Chyun, Seung An | - |
dc.contributor.author | Suh, Myunghyun Paik | - |
dc.date.accessioned | 2023-12-11T07:15:25Z | - |
dc.date.available | 2023-12-11T07:15:25Z | - |
dc.date.created | 2020-11-30 | - |
dc.date.issued | 2014-07 | - |
dc.identifier.citation | Angewandte Chemie - International Edition, Vol.53 No.30, pp.7819-7822 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://hdl.handle.net/10371/198539 | - |
dc.description.abstract | To develop a metal-organic framework (MOF) for hydrogen storage, SNU-200 incorporating a 18-crown-6 ether moiety as a specific binding site for selected cations has been synthesized. SNU-200 binds K+, NH4+, and methyl viologen( MV2+) through single-crystal to single-crystal transformations. It exhibits characteristic gas-sorption properties depending on the bound cation. SNU-200 activated with supercritical CO2 shows a higher isosteric heat (Q(st)) of H-2 adsorption (7.70 kJ mol(-1)) than other zinc-based MOFs. Among the cation inclusions, K+ is the best for enhancing the isosteric heat of the H-2 adsorption (9.92 kJ mol(-1)) as a result of the accessible open metal sites on the K+ ion. | - |
dc.language | 영어 | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.title | Hydrogen Storage in a Potassium-Ion-Bound Metal-Organic Framework Incorporating Crown Ether Struts as Specific Cation Binding Sites | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/anie.201404265 | - |
dc.citation.journaltitle | Angewandte Chemie - International Edition | - |
dc.identifier.wosid | 000339562400021 | - |
dc.identifier.scopusid | 2-s2.0-84904676824 | - |
dc.citation.endpage | 7822 | - |
dc.citation.number | 30 | - |
dc.citation.startpage | 7819 | - |
dc.citation.volume | 53 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Suh, Myunghyun Paik | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | ENHANCED ISOSTERIC HEAT | - |
dc.subject.keywordPlus | CO2 ADSORPTION | - |
dc.subject.keywordPlus | GAS-SORPTION | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | SELECTIVITY | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | CAPACITY | - |
dc.subject.keywordPlus | EXCHANGE | - |
dc.subject.keywordPlus | LIGAND | - |
dc.subject.keywordPlus | PORE | - |
dc.subject.keywordAuthor | cation inclusion | - |
dc.subject.keywordAuthor | crown ethers | - |
dc.subject.keywordAuthor | hydrogen storage | - |
dc.subject.keywordAuthor | metal-organic frameworks | - |
dc.subject.keywordAuthor | potassium ion | - |
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