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CH-pi and CF-pi Interactions Lead to Structural Changes of N-Heterocyclic Carbene Palladium Complexes
Cited 31 time in
Web of Science
Cited 32 time in Scopus
- Authors
- Issue Date
- 2014-01
- Publisher
- John Wiley & Sons Ltd.
- Citation
- Angewandte Chemie - International Edition, Vol.53 No.5, pp.1283-1287
- Abstract
- The role of CH-pi and CF-pi interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using H-1 NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH-pi interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazol-2-ylidene-based [(NHC)(2)PdX2] complexes, while CF-pi interactions led to the exclusive formation of the cis-syn isomer of diiodobis(3-isopropyl-1-pentafluorophenylimidazol-2-ylidene) palladium(II).
- ISSN
- 1433-7851
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