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Pd-catalyzed nucleophilic fluorination of aryl bromides
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- Authors
- Issue Date
- 2014-03
- Publisher
- American Chemical Society
- Citation
- Journal of the American Chemical Society, Vol.136 No.10, pp.3792-3795
- Abstract
- On the basis of mechanism-driven reaction design, a Pd-catalyzed nucleophilic fluorination of aryl bromides and iodides has been developed. The method exhibits a broad substrate scope, especially with respect to nitrogen-containing heteroaryl bromides, and proceeds with minimal formation of the corresponding reduction products. A facilitated ligand modification process was shown to be critical to the success of the reaction. © 2014 American Chemical Society.
- ISSN
- 0002-7863
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