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Chemical Glycosylation with p-Methoxyphenyl (PMP) Glycosides via Oxidative Activation
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Web of Science
Cited 1 time in Scopus
- Authors
- Issue Date
- 2023-05
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, Vol.25 No.19, pp.3471-3475
- Abstract
- A novel persulfate-mediated oxidative glycosylation system using p-methoxyphenyl (PMP) glycosides as bench-stable glycosyl donors is developed. This study shows that both K2S2O8 as an oxidant and Hf(OTf)4 as a Lewis acid catalyst play important roles in the oxidative activation of the PMP group into a potential leaving group. This convenient glycosylation protocol proceeds under mild conditions and delivers a wide range of biologically and synthetically valuable glycoconjugates, including glycosyl fluorides.
- ISSN
- 1523-7060
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