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Synthesis and chemosensitivity of a new iminium salt toward a cyanide anion

Cited 16 time in Web of Science Cited 15 time in Scopus
Authors

Rao, Boddu Ananda; Lee, Jae-Young; Son, Young-A

Issue Date
2014-06
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, Vol.127, pp.268-274
Abstract
A short, high-yielding route to pyranylidene Iminium (Imi) salts using a new pyrylium salt reaction between N,N-Dimethylformamide (DMF) and acetic anhydride is reported. The Imi salt-sensing behavior toward various anions has been investigated using UV-Visible spectroscopy. The Imi salt demonstrates high selectively for CN- when various other anions, such as CN-, Cl-, Br-, I-, SCN-, CIO4-, NO3-, HSO4-, PF6- and N-3(-) are present because it is highly reactive towards nucleophiles. The selective detection of CN- with the Imi unit gave rise to a significant hypochromic shift in the CH3CN solution at lambda(max) = 444 nm and 423 nm and creation of new peak at 252 nm. These studies indicated that CN- had high affinity toward Imi, forming a 1:1 complex; this observation agrees with the current understanding of these materials. (C) 2014 Elsevier B.V. All rights reserved.
ISSN
1386-1425
URI
https://hdl.handle.net/10371/199533
DOI
https://doi.org/10.1016/j.saa.2014.02.052
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  • College of Pharmacy
  • Department of Pharmacy
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