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In situ-generated metal oxide catalyst during CO oxidation reaction transformed from redox-active metal-organic framework-supported palladium nanoparticles
Cited 21 time in
Web of Science
Cited 23 time in Scopus
- Authors
- Issue Date
- 2012-08
- Publisher
- Springer Verlag
- Citation
- Nanoscale Research Letters, Vol.7, p. 461
- Abstract
- The preparation of redox-active metal-organic framework (ra-MOF)-supported Pd nanoparticles (NPs) via the redox couple-driven method is reported, which can yield unprotected metallic NPs at room temperature within 10 min without the use of reducing agents. The Pd@ra-MOF has been exploited as a precursor of an active catalyst for CO oxidation. Under the CO oxidation reaction condition, Pd@ra-MOF is transformed into a PdOx-NiOy/C nanocomposite to generate catalytically active species in situ, and the resultant nanocatalyst shows sustainable activity through synergistic stabilization.
- ISSN
- 1931-7573
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