Publications
Detailed Information
Iron-Catalyzed Acceptorless Dehydrogenative Coupling of Alcohols With Aromatic Diamines: Selective Synthesis of 1,2-Disubstituted Benzimidazoles
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Putta, Ramachandra Reddy | - |
dc.contributor.author | Chun, Simin | - |
dc.contributor.author | Lee, Seok Beom | - |
dc.contributor.author | Oh, Dong-Chan | - |
dc.contributor.author | Hong, Suckchang | - |
dc.date.accessioned | 2024-05-14T07:17:16Z | - |
dc.date.available | 2024-05-14T07:17:16Z | - |
dc.date.created | 2020-07-27 | - |
dc.date.issued | 2020-06 | - |
dc.identifier.citation | Frontiers in Chemistry, Vol.8, p. 429 | - |
dc.identifier.issn | 2296-2646 | - |
dc.identifier.uri | https://hdl.handle.net/10371/202007 | - |
dc.description.abstract | Benzimidazoles are importantN-heteroaromatic compounds with various biological activities and pharmacological applications. Herein, we present the first iron-catalyzed selective synthesis of 1,2-disubstituted benzimidazolesviaacceptorless dehydrogenative coupling of primary alcohols with aromatic diamines. The tricarbonyl (eta(4)-cyclopentadienone) iron complex catalyzed dehydrogenative cyclization, releasing water and hydrogen gas as by-products. The earth abundance and low toxicity of iron metal enable the provision of an eco-friendly and efficient catalytic method for the synthesis of benzimidazoles. | - |
dc.language | 영어 | - |
dc.publisher | Frontiers Media S.A. | - |
dc.title | Iron-Catalyzed Acceptorless Dehydrogenative Coupling of Alcohols With Aromatic Diamines: Selective Synthesis of 1,2-Disubstituted Benzimidazoles | - |
dc.type | Article | - |
dc.identifier.doi | 10.3389/fchem.2020.00429 | - |
dc.citation.journaltitle | Frontiers in Chemistry | - |
dc.identifier.wosid | 000548388600001 | - |
dc.identifier.scopusid | 2-s2.0-85087498703 | - |
dc.citation.startpage | 429 | - |
dc.citation.volume | 8 | - |
dc.description.isOpenAccess | Y | - |
dc.contributor.affiliatedAuthor | Oh, Dong-Chan | - |
dc.contributor.affiliatedAuthor | Hong, Suckchang | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | TRANSFER HYDROGENATION | - |
dc.subject.keywordPlus | TRICARBONYL COMPLEXES | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | METAL | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | AMINES | - |
dc.subject.keywordPlus | SERIES | - |
dc.subject.keywordAuthor | iron catalysis | - |
dc.subject.keywordAuthor | dehydrogenative coupling | - |
dc.subject.keywordAuthor | borrowing hydrogen | - |
dc.subject.keywordAuthor | alcohol | - |
dc.subject.keywordAuthor | benzimidazoles | - |
- Appears in Collections:
- Files in This Item:
- There are no files associated with this item.
Item View & Download Count
Items in S-Space are protected by copyright, with all rights reserved, unless otherwise indicated.