(Bipyridyl-kappa N-2,N &apos;)bis(eta(5)-pentamethylcyclopentadienyl) (trifluoromethane-sulfonato-kappa O)cerium(III)

Kazhdan, Daniel; Chomitz, Wayne A.; Harman, William H.; Hoette, Trisha M.; Park, Cheol-Hwan

doi:10.1107/S1600536807022209

서울대학교 중앙도서관

S-Space 소개

My S-Space

로그인이 필요합니다.

S-Space

Publications

Detailed Information

(Bipyridyl-kappa N-2,N ')bis(eta(5)-pentamethylcyclopentadienyl) (trifluoromethane-sulfonato-kappa O)cerium(III) : (Bipyridyl-[kappa]2N,N')bis([eta]5-pentamethylcyclopentadienyl)(trifluoromethanesulfonato-[kappa]O)cerium(III)

Cited 0 time in Web of Science Cited 0 time in Scopus

Export

Authors: Kazhdan, Daniel; Chomitz, Wayne A.; Harman, William H.; Hoette, Trisha M.; Park, Cheol-Hwan

Issue Date: 2007-06

Publisher: Blackwell Publishing Inc.

Citation: Acta Crystallographica Section E: Structure Reports Online, Vol.63 No.6, pp.M1656-U774

Abstract: The title compound, [ Ce( CF3SO3)( C10H15) (2)( C10H8N2)], crystallizes as a bent metallocene with an inner- sphere trifluoromethanesulfonate ligand [ Cg1 - Ce - Cg2 = 138.91 ( 1) A; Cg1 and Cg2 are the centroids of the cyclopentadienyl rings]. The pentamethylcyclopentadienyl rings have a slightly staggered conformation. The bipyridine ligand has an N - C - C - N torsion angle of - 8.2 ( 7)degrees.