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Mechanistic insight into the aromatic hydroxylation by high-valent Iron(IV)-oxo porphyrin π-cation radical complexes
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kang, Min Jung | - |
dc.contributor.author | Song, Woon Ju | - |
dc.contributor.author | Han, Ah Rim | - |
dc.contributor.author | Choi, Young Sang | - |
dc.contributor.author | Jang, Ho Gyeom | - |
dc.contributor.author | Nam, Won Woo | - |
dc.date.accessioned | 2024-05-20T06:15:19Z | - |
dc.date.available | 2024-05-20T06:15:19Z | - |
dc.date.created | 2024-05-20 | - |
dc.date.created | 2024-05-20 | - |
dc.date.issued | 2007-08 | - |
dc.identifier.citation | The Journal of Organic Chemistry, Vol.72 No.16, pp.6301-6304 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | https://hdl.handle.net/10371/203498 | - |
dc.description.abstract | [GRAPHICS] Mechanistic studies of the aromatic hydroxylation by high-valent iron(IV)-oxo porphyrin pi-cation radicals revealed that the aromatic oxidation involves an initial electrophilic attack on the pi-system of the aromatic ring to produce a tetrahedral radical or cationic sigma-complex. The mechanism was proposed on the basis of experimental results such as a large negative Hammett rho value and an inverse kinetic isotope effect. By carrying out isotope labeling studies, the oxygen in oxygenated products was found to derive from the iron-oxo porphyrin intermediates. | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Mechanistic insight into the aromatic hydroxylation by high-valent Iron(IV)-oxo porphyrin π-cation radical complexes | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/jo070557y | - |
dc.citation.journaltitle | The Journal of Organic Chemistry | - |
dc.identifier.wosid | 000248344400053 | - |
dc.identifier.scopusid | 2-s2.0-34547624183 | - |
dc.citation.endpage | 6304 | - |
dc.citation.number | 16 | - |
dc.citation.startpage | 6301 | - |
dc.citation.volume | 72 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Song, Woon Ju | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | WATER-SOLUBLE METALLOPORPHYRINS | - |
dc.subject.keywordPlus | OXO-HYDROXO TAUTOMERISM | - |
dc.subject.keywordPlus | CYTOCHROME-P450 ENZYMES | - |
dc.subject.keywordPlus | MODEL REACTIONS | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | EPOXIDATION | - |
dc.subject.keywordPlus | METABOLISM | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | P450 | - |
dc.subject.keywordPlus | INTERMEDIATE | - |
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