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Structure and reactivity of [(L.Pd)(n).(1,5-cyclooctadiene)] (n=1-2) complexes bearing biaryl phosphine ligands : Structure and reactivity of [(L·Pd)n·(1,5-cyclooctadiene)] (n = 1-2) complexes bearing biaryl phosphine ligands
DC Field | Value | Language |
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dc.contributor.author | Lee, Hong Geun | - |
dc.contributor.author | Milner, Phillip J. | - |
dc.contributor.author | Andreas, Loren | - |
dc.contributor.author | Colvin, Michael T. | - |
dc.contributor.author | Buchwald, Stephen L. | - |
dc.date.accessioned | 2024-05-21T02:25:57Z | - |
dc.date.available | 2024-05-21T02:25:57Z | - |
dc.date.created | 2024-04-22 | - |
dc.date.issued | 2014-10 | - |
dc.identifier.citation | Inorganica Chimica Acta, Vol.422, pp.188-192 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.uri | https://hdl.handle.net/10371/203567 | - |
dc.description.abstract | The structure of the stable Pd(0) precatalyst [(1,5-cyclooctadiene)(L.Pd)(2)] = AdBrettPhos) for the Pd-catalyzed fluorination of aryl triflates has been further studied by solid state NMR and X-ray cystrallography of the analogous N-phenylmaleimide complex. The reactivity of this complex with CDCl3 to form a dearomatized complex is also presented. In addition, studies suggest that related bulky biaryl phosphine ligands form similar complexes, although the smaller ligand BrettPhos forms a monomeric [(1,5-cyclooctadiene)(L.Pd)] species instead. (C) 2014 Elsevier By. All rights reserved. | - |
dc.language | 영어 | - |
dc.publisher | Elsevier BV | - |
dc.title | Structure and reactivity of [(L.Pd)(n).(1,5-cyclooctadiene)] (n=1-2) complexes bearing biaryl phosphine ligands | - |
dc.title.alternative | Structure and reactivity of [(L·Pd)n·(1,5-cyclooctadiene)] (n = 1-2) complexes bearing biaryl phosphine ligands | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.ica.2014.06.008 | - |
dc.citation.journaltitle | Inorganica Chimica Acta | - |
dc.identifier.wosid | 000343585800027 | - |
dc.identifier.scopusid | 2-s2.0-84908011426 | - |
dc.citation.endpage | 192 | - |
dc.citation.startpage | 188 | - |
dc.citation.volume | 422 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Lee, Hong Geun | - |
dc.type.docType | 원저(Article) | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | IN-SITU | - |
dc.subject.keywordPlus | CATALYST | - |
dc.subject.keywordPlus | FLUORINATION | - |
dc.subject.keywordAuthor | Pd(0) complex | - |
dc.subject.keywordAuthor | Precatalyst | - |
dc.subject.keywordAuthor | Biaryl phosph ne | - |
dc.subject.keywordAuthor | Oxidative addition | - |
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