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Valence-state transition in SrMn 1-xMo xO 3 (0≤x≤0.5) investigated by soft x-ray absorption spectroscopy : Valence-state transition in SrMn<sub>1-<i>x</i></sub>Mo<i><sub>x</sub></i>O<sub>3</sub> (0 ≤ <i>x</i> ≤ 0.5) investigated by soft x-ray absorption spectroscopy
DC Field | Value | Language |
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dc.contributor.author | Lee, Jieun | - |
dc.contributor.author | Kim, Bongjae | - |
dc.contributor.author | Kim, B. H. | - |
dc.contributor.author | Min, B. I. | - |
dc.contributor.author | Kolesnik, S. | - |
dc.contributor.author | Chmaissem, O. | - |
dc.contributor.author | Mais, J. | - |
dc.contributor.author | Dabrowski, B. | - |
dc.contributor.author | Shin, H. J. | - |
dc.contributor.author | Kim, D. H. | - |
dc.contributor.author | Lee, H. J. | - |
dc.contributor.author | Kang, J. -S. | - |
dc.date.accessioned | 2024-05-21T02:26:45Z | - |
dc.date.available | 2024-05-21T02:26:45Z | - |
dc.date.created | 2024-05-21 | - |
dc.date.created | 2024-05-21 | - |
dc.date.created | 2024-05-21 | - |
dc.date.issued | 2009-11 | - |
dc.identifier.citation | PHYSICAL REVIEW B, Vol.80 No.20 | - |
dc.identifier.issn | 1098-0121 | - |
dc.identifier.uri | https://hdl.handle.net/10371/203582 | - |
dc.description.abstract | The electronic structures of perovskite SrMn1-xMoxO3 (0 <= x <= 0.5) have been investigated by employing soft x-ray absorption spectroscopy (XAS). Mn 2p XAS shows the systematic change in the valence states of Mn ions in SrMn1-xMoxO3 due to the substitution of hexavalent Mo6+(4d(0)) ions. With increasing x, the valence states and the spin configurations of Mn ions change from high-spin (HS) Mn4+ for x=0, to HS Mn3+(t(2g)(3)up arrow e(g)(1)up arrow) for x=0.3, and HS Mn2+(t(2g)(3)up arrow e(g)(2)up arrow) for x=0.5. The measured Mn 2p XAS spectra are described well with the configuration interaction (CI) cluster model, including the Jahn-Teller distortion effect for Mn3+ ions. The combination of the findings of Mn 2p XAS and the CI calculations provides the complete picture of the electronic structures of SrMn1-xMoxO3 for 0 <= x <= 0.5. | - |
dc.language | 영어 | - |
dc.publisher | AMER PHYSICAL SOC | - |
dc.title | Valence-state transition in SrMn 1-xMo xO 3 (0≤x≤0.5) investigated by soft x-ray absorption spectroscopy | - |
dc.title.alternative | Valence-state transition in SrMn1-xMoxO3 (0 ≤ x ≤ 0.5) investigated by soft x-ray absorption spectroscopy | - |
dc.type | Article | - |
dc.identifier.doi | 10.1103/PhysRevB.80.205112 | - |
dc.citation.journaltitle | PHYSICAL REVIEW B | - |
dc.identifier.wosid | 000272311400040 | - |
dc.identifier.scopusid | 2-s2.0-84856366287 | - |
dc.citation.number | 20 | - |
dc.citation.volume | 80 | - |
dc.description.isOpenAccess | Y | - |
dc.contributor.affiliatedAuthor | Lee, Jieun | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | ELECTRONIC-STRUCTURE | - |
dc.subject.keywordPlus | PEROVSKITE | - |
dc.subject.keywordPlus | OXIDES | - |
dc.subject.keywordPlus | PHOTOEMISSION | - |
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