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An electrochemically controllable nanomechanical molecular system utilizing edge-to-face and face-to-face aromatic interactions
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Heon Gon | - |
dc.contributor.author | Lee, Chi Wan | - |
dc.contributor.author | Yun, Sung Goo | - |
dc.contributor.author | Hong, Byung Hee | - |
dc.contributor.author | Kim, Young Ok | - |
dc.contributor.author | Kim, Dongwook | - |
dc.contributor.author | Ihm, Hyejae | - |
dc.contributor.author | Lee, Jung Woo | - |
dc.contributor.author | Lee, Eun Cheol | - |
dc.contributor.author | Tarakeshwar P. | - |
dc.contributor.author | Park, Su Moon | - |
dc.contributor.author | Kim, Kwang S. | - |
dc.date.accessioned | 2024-07-12T02:10:29Z | - |
dc.date.available | 2024-07-12T02:10:29Z | - |
dc.date.created | 2024-06-19 | - |
dc.date.issued | 2002-10 | - |
dc.identifier.citation | Organic Letters, Vol.4 No.22, pp.3971-3974 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://hdl.handle.net/10371/204679 | - |
dc.description.abstract | [GRAPHICS] A new molecular system, 2,11-dithio[4,4]metametaquinocyclophane containing a quinone moiety; was designed and synthesized. As the quinone moiety can readily be converted into an aromatic pi-system (hydroquinone) upon reduction, the nanomechanical molecular cyclophane system exhibits a large flapping motion like a molecular flipper from the electrochemical redox process. The conformational changes upon reduction and oxidation are caused by changes of nonbonding interaction forces (devoid of bond formation/breaking) from the edge-to-face to face-to-face aromatic interactions and vice versa, respectively. | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | An electrochemically controllable nanomechanical molecular system utilizing edge-to-face and face-to-face aromatic interactions | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ol0268541 | - |
dc.citation.journaltitle | Organic Letters | - |
dc.identifier.wosid | 000178877500050 | - |
dc.identifier.scopusid | 2-s2.0-19044383051 | - |
dc.citation.endpage | 3974 | - |
dc.citation.number | 22 | - |
dc.citation.startpage | 3971 | - |
dc.citation.volume | 4 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Hong, Byung Hee | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | CATION-PI INTERACTIONS | - |
dc.subject.keywordPlus | BENZENE DIMER | - |
dc.subject.keywordPlus | ORIGIN | - |
dc.subject.keywordPlus | SWITCH | - |
dc.subject.keywordPlus | RECEPTORS | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | CLUSTER | - |
dc.subject.keywordPlus | ARRAYS | - |
dc.subject.keywordPlus | ROTOR | - |
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