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Salinazinones A and B: Pyrrolidinyl-Oxazinones from Solar Saltern-Derived Streptomyces sp KMF-004
Cited 29 time in
Web of Science
Cited 31 time in Scopus
- Authors
- Issue Date
- 2015-10
- Publisher
- American Chemical Society
- Citation
- Organic Letters, Vol.17 No.20, pp.5024-5027
- Abstract
- Salinazinones A (1) and B (2), two unprecedented pyrrolidinyl-oxazinones, were isolated from the culture broth of Streptomyces sp. KMF-004 from a solar saltern at Aphae Island, Korea. The structures of these salinazinones, which are unusual and consist of 2-methylpropenyl-1,3-oxazin-6-one bearing 1-oxopyrrolidinyl substituents, were assigned by spectral and chemical analyses using Mosher's method, circular dichroism (CD), and calculated ECD. Salinazinones are the first examples of a natural alkaloid class composed of an oxazinone-pyrrolidone conjugate.
- ISSN
- 1523-7060
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