A highly efficient wide-band-gap host material for blue electrophosphorescent light-emitting devices

Abstract

We report on an efficient wide-band-gap host material for blue electrophosphorescence devices, namely, 1,2-trans-di-9-carbazolylcyclobutane (DCz). Photophysical studies show that lower-energy excimer formation between the carbazole units can be efficiently suppressed in a DCz film, thus maintaining its high triplet-state energy and inducing an exothermic energy transfer from DCz to iridium(III)bis[(4,6-difluorophenyl)-pyridinato-N,C2]picolinate (FIrpic). Electrophosphorescent devices comprising a FIrpic:DCz emitting layer exhibit a superior performance with a maximum external quantum efficiency of 9.8%, a maximum luminance efficiency of 21.5 cd/A, and a maximum power efficiency of 15.0 lm/W at 0.01 mA/cm2.