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Fine Tuning of Molecular Energy Level of Low Band Gap Polymer by Introduction of Fluorine for High Performance Organic Photovoltaics

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Authors

박정하; 정재웅; 조원호

Issue Date
2012
Publisher
한국고분자학회
Citation
2012 춘계학술대회 연구논문 초록집, 제37권 1호, p. 88
Keywords
공학
Abstract
Band gap and molecular energy level of alternating conjugated copolymers are the most important parameters to achieve high efficient organic photovoltatcs. Lowering
the HOMO energy level of donor polymer is beneficial for achieving high open circuit voltage(Voc). One of the easy and simple methods to lower the HOMO energy level
of alternating conjugated copolymer is to introduce the electron-withdrawing group onto the polymer backbone. For this purpose, fluorinated phenyl group is alternatively
copolymerized with diketopyrrolo[3,4-c]pyrrole (OPP) which is one of promising building blocks for low band gap alternating copolymer. In this work, we have systematically
synthesized low band gap copolymers composed of difluoro or tetrafluorophenylene and DPP. The effect of the number of fluorine substitution of the polymer on their
electrochemical and photovoltaic properties will be demonstrated.
Language
English
URI
https://hdl.handle.net/10371/81408
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