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CH-π and CF-π Interactions Lead to Structural Changes of N-Heterocyclic Carbene Palladium Complexes
Cited 29 time in
Web of Science
Cited 30 time in Scopus
- Authors
- Issue Date
- 2014-01
- Publisher
- Wiley-VCH Verlag
- Citation
- Angewandte Chemie-International edition, Vol.53 No.5, pp. 1283-1287
- Keywords
- 복합학
- Abstract
- The role of CH–π and CF–π interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using 1H NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH–π interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazol-2-ylidene-based [(NHC)2PdX2] complexes, while CF–π interactions led to the exclusive formation of the cis-syn isomer of diiodobis(3-isopropyl-1-pentafluorophenylimidazol-2-ylidene) palladium(II).
- ISSN
- 1433-7851
- Language
- English
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