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Involvement of high-valent manganese-oxo intermediates in oxidation reactions: realisation in nature, nano and molecular systems

Cited 10 time in Web of Science Cited 10 time in Scopus
Authors
Balamurugan, Mani; Saravanan, Natarajan; Ha, Heonjin; Lee, Yoon Ho; Nam, Ki Tae
Issue Date
2018-07-04
Publisher
Springer Open
Citation
Nano Convergence, 5(1):18
Keywords
High-valentMn-oxoOECRNRBiomimetic
Abstract
Abstract
Manganese plays multiple role in many biological redox reactions in which it exists in different oxidation states from Mn(II) to Mn(IV). Among them the high-valent manganese-oxo intermediate plays important role in the activity of certain enzymes and lessons from the natural system provide inspiration for new developments of artificial systems for a sustainable energy supply and various organic conversions. This review describes recent advances and key lessons learned from the nature on high-valent Mn-oxo intermediates. Also we focus on the elemental science developed from the natural system, how the novel strategies are realised in nano particles and molecular sites at heterogeneous and homogeneous reaction conditions respectively. Finally, perspectives on the utilisation of the high-valent manganese-oxo species towards other organic reactions are proposed.
ISSN
2196-5404
Language
English
URI
http://hdl.handle.net/10371/142840
DOI
https://doi.org/10.1186/s40580-018-0150-5
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Material Science and Engineering (재료공학부) Journal Papers (저널논문_재료공학부)
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