synthesis of chiral 2,3-diamino acid derivatives using diaza-cope rearrangement
- Issue Date
- 서울대학교 대학원
- 학위논문 (석사)-- 서울대학교 대학원 : 화학부, 2012. 2. 김병문.
- Chiral vicinal diamine derivatives are important starting materials not only for stereoselctive catalysts, but also for diverse durgs. Because of this reasons, many interesting chiral vicinal diamine derivatives have been synthesized by oxidation, reduction, reductive coupling, C-C bond forming reactions and chiral resolutions. We developed a stereospecific synthesis of chiral vicinal α-β-diamino ester Using diaza-Cope rearrangement reaction.
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