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Enantioselective synthesis of the lomaiviticin aglycon full carbon skeleton reveals remarkable remote substituent effects during the dimerization event
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Cited 40 time in Scopus
- Authors
- Issue Date
- 2010
- Publisher
- John Wiley & Sons Ltd.
- Citation
- Chemistry - A European Journal, Vol.16 No.44, pp.13058-13062
- Abstract
- A full carbon skeleton of the natural product lomaiviticin has been synthesized. The approach features anionic annulation reactions to deliver A and B rings of the natural product, and stereoselective oxidative enolate coupling to form the central C2-C2′ σ bond. In the course of the investigation, a remarkable substituent effect at C11 position was observed. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
- ISSN
- 0947-6539
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