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N-(triphenylphosphoranylidene) aniline as a novel electrolyte additive for high voltage LiCoO2 operations in lithium ion batteries

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dc.contributor.authorLee, Je-Nam-
dc.contributor.authorHan, Gi-Beom-
dc.contributor.authorRyou, Myung-Hyun-
dc.contributor.authorLee, Dong Jin-
dc.contributor.authorSong, Jongchan-
dc.contributor.authorChoi, Jang Wook-
dc.contributor.authorPark, Jung-Ki-
dc.date.accessioned2020-03-16T11:07:45Z-
dc.date.available2020-03-16T11:07:45Z-
dc.date.created2018-07-02-
dc.date.issued2011-05-
dc.identifier.citationElectrochimica Acta, Vol.56 No.14, pp.5195-5200-
dc.identifier.issn0013-4686-
dc.identifier.other38490-
dc.identifier.urihttps://hdl.handle.net/10371/164624-
dc.description.abstractWe report N-(triphenylphosphoranylidene) aniline (TPPA) as a new electrolyte additive for high performance lithium cobalt oxide (LiCoO2) electrodes during high voltage operations. When cycled in the voltage range of 3.0-4.4 V. graphite-LiCoO2 full cells with 0.2 wt%TPPA exhibited 10% increased discharge capacities after 200 cycles compared to those of control cells with no such additive. The enhanced cycling performance is attributed to the additive effect toward the modified surface films on LiCoO2 electrodes that suppress the decomposition of both solvent and salt in the electrolyte. This additive effect was characterized by electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS). (C) 2011 Elsevier Ltd. All rights reserved.-
dc.language영어-
dc.publisherPergamon Press Ltd.-
dc.titleN-(triphenylphosphoranylidene) aniline as a novel electrolyte additive for high voltage LiCoO2 operations in lithium ion batteries-
dc.typeArticle-
dc.contributor.AlternativeAuthor최장욱-
dc.identifier.doi10.1016/j.electacta.2011.03.041-
dc.citation.journaltitleElectrochimica Acta-
dc.identifier.wosid000291907300039-
dc.identifier.scopusid2-s2.0-79956373112-
dc.citation.endpage5200-
dc.citation.number14-
dc.citation.startpage5195-
dc.citation.volume56-
dc.identifier.sci000291907300039-
dc.description.isOpenAccessN-
dc.contributor.affiliatedAuthorChoi, Jang Wook-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.subject.keywordPlusCATHODE MATERIALS-
dc.subject.keywordPlusFUNCTIONAL ELECTROLYTES-
dc.subject.keywordPlusPERFORMANCE-
dc.subject.keywordPlusSTORAGE-
dc.subject.keywordPlusCELLS-
dc.subject.keywordPlusXPS-
dc.subject.keywordAuthorAdditive-
dc.subject.keywordAuthorN-(triphenylphosphoranylidene) aniline (TPPA)-
dc.subject.keywordAuthorLithium cobalt oxide (LiCoO2)-
dc.subject.keywordAuthorHigh voltage operation-
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  • College of Engineering
  • School of Chemical and Biological Engineering
Research Area Carbon nanotube, Graphene, Lithium-ion battery, Lithium-sulfur battery, Silicon anode

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