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Self-assembled Fe3O4 nanoparticle clusters as high-performance anodes for lithium ion batteries via geometric confinement

Cited 274 time in Web of Science Cited 285 time in Scopus
Authors
Lee, Soo Hong; Yu, Seung-Ho; Lee, Ji Eun; Jin, Aihua; Lee, Dong Jun; Lee, Nohyun; Jo, Hyungyung; Shin, Kwangsoo; Ahn, Tae-Young; Kim, Young-Woon; Choe, Heeman; Sung, Yung-Eun; Hyeon, Taeghwan
Issue Date
2013-09
Citation
Nano Letters, Vol.13 No.9, pp.4249-4256
Keywords
Nanoparticleslithium ion batteriesself-assemblysolid-electrolyte interphaseiron oxideanodes
Abstract
Although different kinds of metal oxide nanoparticles continue to be proposed as anode materials for lithium ion batteries (LIBs), their cycle life and power density are still not suitable for commercial applications. Metal oxide nanoparticles have a large storage capacity, but they suffer from the excessive generation of solid electrolyte interphase (SEI) on the surface, low electrical conductivity, and mechanical degradation and pulverization resulted from severe volume expansion during cycling. Herein we present the preparation of mesoporous iron oxide nanoparticle clusters (MIONCs) by a bottom-up self-assembly approach and demonstrate that they exhibit excellent cyclic stability and rate capability derived from their three-dimensional mesoporous nanostructure. By controlling the geometric configuration, we can achieve stable interfaces between the electrolyte and active materials, resulting in SEI formation confined on the outer surface of the MIONCs.
ISSN
1530-6984
URI
http://hdl.handle.net/10371/166180
DOI
https://doi.org/10.1021/nl401952h
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Chemical Convergence for Energy and Environment (에너지환경 화학융합기술전공)Journal Papers (저널논문_에너지환경 화학융합기술전공)
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