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Polymerizations with elemental sulfur: A novel route to high sulfur content polymers for sustainability, energy and defense
DC Field | Value | Language |
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dc.contributor.author | Griebel, Jared J. | - |
dc.contributor.author | Glass, Richard S. | - |
dc.contributor.author | Char, Kookheon | - |
dc.contributor.author | Pyun, Jeffrey | - |
dc.date.accessioned | 2023-04-19T08:46:46Z | - |
dc.date.available | 2023-04-19T08:46:46Z | - |
dc.date.created | 2018-07-05 | - |
dc.date.created | 2018-07-05 | - |
dc.date.issued | 2016-07 | - |
dc.identifier.citation | Progress in Polymer Science, Vol.58, pp.90-125 | - |
dc.identifier.issn | 0079-6700 | - |
dc.identifier.uri | https://hdl.handle.net/10371/191164 | - |
dc.description.abstract | Recent developments in the polymerizations of elemental sulfur (S-8) to prepare high sulfur content polymers are reviewed. While the homopolymerization of S-8 via ring-opening processes to prepare high molar mass polymeric sulfur has long been known, this form of polymeric sulfur is chemically unstable and depolymerizes back to S-8. In the current report, we discuss the background into the production of sulfur via petroleum refining and the challenges associated with utilizing S-8 as a chemical reagent for materials synthesis. To circumvent these long standing challenges in working with sulfur, the use of S-8 as a reaction medium and comonomer in a process termed, inverse vulcanization, was developed to prepare chemically stable and processable sulfur copolymers. Furthermore, access to polymeric materials with a very high content of sulfur-sulfur (S-S) bonds enabled for the first time the creation of materials with useful (electro)chemical and optical properties which are reviewed for use in Li-S batteries, IR imaging technology and self-healing materials. (C) 2016 Published by Elsevier Ltd. | - |
dc.language | 영어 | - |
dc.publisher | Elsevier BV | - |
dc.title | Polymerizations with elemental sulfur: A novel route to high sulfur content polymers for sustainability, energy and defense | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.progpolymsci.2016.04.003 | - |
dc.citation.journaltitle | Progress in Polymer Science | - |
dc.identifier.wosid | 000378673200004 | - |
dc.identifier.scopusid | 2-s2.0-84992297279 | - |
dc.citation.endpage | 125 | - |
dc.citation.startpage | 90 | - |
dc.citation.volume | 58 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Char, Kookheon | - |
dc.type.docType | Review | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | HIGH REFRACTIVE-INDEX | - |
dc.subject.keywordPlus | COMPOSITE CATHODE MATERIALS | - |
dc.subject.keywordPlus | DYNAMIC COVALENT POLYMERS | - |
dc.subject.keywordPlus | LI-S BATTERIES | - |
dc.subject.keywordPlus | FRAGMENTATION CHAIN TRANSFER | - |
dc.subject.keywordPlus | CROSS-LINKED POLYMERS | - |
dc.subject.keywordPlus | CORE-SHELL STRUCTURE | - |
dc.subject.keywordPlus | ONE-POT SYNTHESIS | - |
dc.subject.keywordPlus | PI-PI STACKING | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE | - |
dc.subject.keywordAuthor | Sulfur polymers | - |
dc.subject.keywordAuthor | Inverse vulcanization | - |
dc.subject.keywordAuthor | Sulfur polymerization | - |
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