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Strongly coupled cyclometalated ruthenium triarylamine chromophores as sensitizers for DSSCs
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kreitner, Christoph | - |
dc.contributor.author | Mengel, Andreas K. C. | - |
dc.contributor.author | Lee, Tae Kyung | - |
dc.contributor.author | Cho, Woohyung | - |
dc.contributor.author | Char, Kookheon | - |
dc.contributor.author | Kang, Yong Soo | - |
dc.contributor.author | Heinze, Katja | - |
dc.date.accessioned | 2023-04-19T08:47:07Z | - |
dc.date.available | 2023-04-19T08:47:07Z | - |
dc.date.created | 2018-07-05 | - |
dc.date.created | 2018-07-05 | - |
dc.date.issued | 2016-06 | - |
dc.identifier.citation | Chemistry - A European Journal, Vol.22 No.26, pp.8915-8928 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | https://hdl.handle.net/10371/191168 | - |
dc.description.abstract | A series of anchor-functionalized cyclometalated bis(tridentate) ruthenium(II) triarylamine hybrids [Ru(dbp-X)(tctpy)](2-) [2a](2-)-[2c](2-) (H(3)tctpy=2,2';6',2 ''-terpyridine-4,4',4 ''-tricarboxylic acid; dpbH=1,3-dipyridylbenzene; X=N(4-C6H4OMe)(2) ([2a](2-)), NPh2 ([2b](2-)), N-carbazolyl [2c](2-)) was synthesized and characterized. All complexes show broad absorption bands in the range 300-700 nm with a maximum at about 545 nm. Methyl esters [Ru(Me3tctpy)(dpb-X)](+) [1a](+)-[1c](+) are oxidized to the strongly coupled mixed-valent species [1a](2+)-[1c](2+) and the RuIII(aminium) complexes [1a](3+)-[1c](3+) at comparably low oxidation potentials. Theoretical calculations suggest an increasing spin delocalization between the metal center and the triarylamine unit in the order [1a]2(+)<[1b](2+)<[1c](2+). Solar cells were prepared with the saponified complexes [2a](2-)-[2c](2-) and the reference dye N719 as sensitizers using the I-3(-)/I- couple and [Co(bpy)3](3+/2+) and [Co(ddpd)2](3+/2+) couples as [B(C6F5)(4)](-) salts as electrolytes (bpy=2,2'-bipyridine; ddpd=N,N'-dimethyl-N,N'-dipyridin-2-yl-pyridine-2,6-diamine). Cells with [2c](2-) and I-3(-)/I- electrolyte perform similarly to cells with N719. In the presence of cobalt electrolytes, all efficiencies are reduced, yet under these conditions [2c](2-) outperforms N719. | - |
dc.language | 영어 | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.title | Strongly coupled cyclometalated ruthenium triarylamine chromophores as sensitizers for DSSCs | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/chem.201601001 | - |
dc.citation.journaltitle | Chemistry - A European Journal | - |
dc.identifier.wosid | 000380270500030 | - |
dc.identifier.scopusid | 2-s2.0-84970969164 | - |
dc.citation.endpage | 8928 | - |
dc.citation.number | 26 | - |
dc.citation.startpage | 8915 | - |
dc.citation.volume | 22 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Char, Kookheon | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | GAUSSIAN-BASIS SETS | - |
dc.subject.keywordPlus | SOLAR-CELLS | - |
dc.subject.keywordPlus | CHARGE-TRANSFER | - |
dc.subject.keywordPlus | NANOCRYSTALLINE TIO2 | - |
dc.subject.keywordPlus | MIXED-VALENCE | - |
dc.subject.keywordPlus | BIS(TRIDENTATE)RUTHENIUM(II) COMPLEXES | - |
dc.subject.keywordPlus | PHOTOVOLTAIC PERFORMANCE | - |
dc.subject.keywordPlus | PHOTOPHYSICAL PROPERTIES | - |
dc.subject.keywordPlus | POLYPYRIDINE COMPLEXES | - |
dc.subject.keywordPlus | ELECTRON-TRANSFER | - |
dc.subject.keywordAuthor | cobalt electrolytes | - |
dc.subject.keywordAuthor | cyclometalated complexes | - |
dc.subject.keywordAuthor | dye-sensitized solar cells | - |
dc.subject.keywordAuthor | mixed valency | - |
dc.subject.keywordAuthor | ruthenium | - |
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