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Orthogonal Reactivity of Acyl Azides in C–H Activation: Dichotomy between C–C and C–N Amidations Based on Catalyst Systems : Orthogonal Reactivity of Acyl Azides in C-H Activation: Dichotomy between C-C and C-N Amidations Based on Catalyst Systems
Cited 86 time in
Web of Science
Cited 91 time in Scopus
- Authors
- Issue Date
- 2014-04
- Publisher
- American Chemical Society
- Citation
- Organic Letters, Vol.16 No.7, pp.2022-2025
- Abstract
- The dual reactivity of acyl azides was utilized successfully in C-H activation by the choice of catalyst systems: while selective C-C amidation was achieved under thermal Rh catalysis, a Ru catalyst was found to mediate direct C-N amidation also highly selectively. Investigations of the mechanistic dichotomy between two catalytic systems are also presented.
- ISSN
- 1523-7060
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