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Rhodium-Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines : Rhodium-Catalyzed Direct C-H Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines
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Cited 257 time in Scopus
- Authors
- Issue Date
- 2012-09
- Publisher
- John Wiley & Sons Ltd.
- Citation
- Angewandte Chemie International Edition, Vol.51 No.39, pp.9904-9908
- Abstract
- No muss, no fuss: A rhodium-catalyzed direct intermolecular C-H amination of benzamides and ketoximes using aryl azides as the amine source has been developed. The reaction exhibits a broad substrate scope with excellent functional-group tolerance, requires no external oxidants, releases N 2 as the only by-product, and produces diarylamines in high yields. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
- ISSN
- 1433-7851
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