Rhodium-Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines

Ryu, Jaeyune; Shin, Kwangmin; Park, Sae Hume; Kim, Ji Young; Chang, Sukbok

doi:10.1002/anie.201205723

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Rhodium-Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines : Rhodium-Catalyzed Direct C-H Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines

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Authors: Ryu, Jaeyune; Shin, Kwangmin; Park, Sae Hume; Kim, Ji Young; Chang, Sukbok

Issue Date: 2012-09

Publisher: John Wiley & Sons Ltd.

Citation: Angewandte Chemie International Edition, Vol.51 No.39, pp.9904-9908

Abstract: No muss, no fuss: A rhodium-catalyzed direct intermolecular C-H amination of benzamides and ketoximes using aryl azides as the amine source has been developed. The reaction exhibits a broad substrate scope with excellent functional-group tolerance, requires no external oxidants, releases N 2 as the only by-product, and produces diarylamines in high yields. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.