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Rhodium-Catalyzed Intermolecular Amidation of Arenes with Sulfonyl Azides via Chelation-Assisted C–H Bond Activation : Rhodium-Catalyzed Intermolecular Amidation of Arenes with Sulfonyl Azides via Chelation-Assisted C-H Bond Activation
Cited 388 time in
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Cited 397 time in Scopus
- Authors
- Issue Date
- 2012-06
- Publisher
- American Chemical Society
- Citation
- Journal of the American Chemical Society, Vol.134 No.22, pp.9110-9113
- Abstract
- We report the direct amidation of arene C-H bonds using sulfonyl azides as the amino source to release N-2 as the single byproduct. The reaction is catalyzed by a cationic rhodium complex under external oxidant-free conditions in the atmospheric environment. A broad range of chelate group-containing arenes are selectively amidated with excellent functional group tolerance, thus opening a new avenue to practical intermolecular C-N bond formation.
- ISSN
- 0002-7863
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