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A Versatile Rhodium(I) Catalyst System for the Addition of Heteroarenes to both Alkenes and Alkynes by a CH Bond Activation : A Versatile Rhodium(I) Catalyst System for the Addition of Heteroarenes to both Alkenes and Alkynes by a C-H Bond Activation
Cited 130 time in
Web of Science
Cited 134 time in Scopus
- Authors
- Issue Date
- 2012-04
- Publisher
- John Wiley & Sons Ltd.
- Citation
- Angewandte Chemie International Edition, Vol.51 No.15, pp.3677-3681
- Abstract
- Rhod to Addition: A highly efficient and convenient rhodium catalyst system was developed for the title transformation. A base co-catalyst was found to facilitate the key arene CH bond-activation step and substrate scope was very broad, including both electron-deficient pyridine N-oxides, and electron-rich azoles. The catalytic system was effective for the hydroheteroarylation of both alkenes and alkynes and gave excellent regio- and stereoselectivity.
- ISSN
- 1433-7851
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