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Chemoselective Primary Amination of Aryl Boronic Acids by PIII/PV═O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO : Chemoselective Primary Amination of Aryl Boronic Acids by P-III/P-V=O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO
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Cited 16 time in Scopus
- Authors
- Issue Date
- 2022-05
- Publisher
- American Chemical Society
- Citation
- Journal of the American Chemical Society, Vol.144 No.20, pp.8902-8907
- Abstract
- A catalytic approach to intercept the transient HNO for a chemoselective primary amination of arylboronic acids isreported. A phosphetane-based catalyst operating within PIII/PV???O redox cycling is shown to capture HNO, generated in situ byNef decomposition of 2-nitropropane, to selectively install the primary amino group at aryl Csp2centers. The method furnishesversatile primary arylamines from arylboronic acid substrates with the preservation of otherwise reactive functional groups
- ISSN
- 0002-7863
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