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Ir(III)-Catalyzed Stereoselective Haloamidation of Alkynes Enabled by Ligand Participation
Cited 28 time in
Web of Science
Cited 29 time in Scopus
- Authors
- Issue Date
- 2018-10
- Publisher
- American Chemical Society
- Citation
- Journal of the American Chemical Society, Vol.140 No.39, pp.12359-12363
- Abstract
- Described herein is the application of a strategy of ligand participation for the Ir-catalyzed imido transfer into alkynes. On the basis of a stoichiometric [3 + 2] cycloaddition of Cp*Ir(III)(kappa(2)-N,O-chelate) with alkynyl dioxazolone, a catalytic haloamidation was developed for the first time by employing [Cp*IrCl2](2) precatalyst and NaX salts (X = Cl or Br) as practical halide sources to furnish synthetically versatile Z-(halovinyl)lactams with excellent stereoselectivity.
- ISSN
- 0002-7863
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