Epitaxial Growth of Molecular Crystals on van der Waals Substrates for High-Performance Organic Electronics

Abstract

Epitaxial van der Waals (vdW) heterostructures of organic and layered materials are demonstrated to create high-performance organic electronic devices. High-quality rubrene films with large single-crystalline domains are grown on h-BN dielectric layers via vdW epitaxy. In addition, high carrier mobility comparable to free-standing single-crystal counterparts is achieved by forming interfacial electrical contacts with graphene electrodes. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.