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Nanoscale Atoms in Solid-State Chemistry

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dc.contributor.authorRoy, Xavier-
dc.contributor.authorLee, Chul-Ho-
dc.contributor.authorCrowther, Andrew C.-
dc.contributor.authorSchenck, Christine L.-
dc.contributor.authorBesara, Tiglet-
dc.contributor.authorLalancette, Roger A.-
dc.contributor.authorSiegrist, Theo-
dc.contributor.authorStephens, Peter W.-
dc.contributor.authorBrus, Louis E.-
dc.contributor.authorKim, Philip-
dc.contributor.authorSteigerwald, Michael L.-
dc.contributor.authorNuckolls, Colin-
dc.date.accessioned2024-05-16T01:16:20Z-
dc.date.available2024-05-16T01:16:20Z-
dc.date.created2023-04-19-
dc.date.created2023-04-19-
dc.date.issued2013-07-
dc.identifier.citationScience, Vol.341 No.6142, pp.157-160-
dc.identifier.issn0036-8075-
dc.identifier.urihttps://hdl.handle.net/10371/202330-
dc.description.abstractWe describe a solid-state material formed from binary assembly of atomically precise molecular clusters. [Co6Se8(PEt3)(6)][C-60](2) and [Cr6Te8(PEt3)(6)][C-60](2) assembled into a superatomic relative of the cadmium iodide (CdI2) structure type. These solid-state materials showed activated electronic transport with activation energies of 100 to 150 millielectron volts. The more reducing cluster Ni9Te6(PEt3)(8) transferred more charge to the fullerene and formed a rock-salt-related structure. In this material, the constituent clusters are able to interact electronically to produce a magnetically ordered phase at low temperature, akin to atoms in a solid-state compound.-
dc.language영어-
dc.publisherAmerican Association for the Advancement of Science-
dc.titleNanoscale Atoms in Solid-State Chemistry-
dc.typeArticle-
dc.identifier.doi10.1126/science.1236259-
dc.citation.journaltitleScience-
dc.identifier.wosid000321965300038-
dc.identifier.scopusid2-s2.0-84880251973-
dc.citation.endpage160-
dc.citation.number6142-
dc.citation.startpage157-
dc.citation.volume341-
dc.description.isOpenAccessY-
dc.contributor.affiliatedAuthorLee, Chul-Ho-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusPEROVSKITES-
dc.subject.keywordPlusFULLERIDES-
dc.subject.keywordPlusSALTS-
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  • College of Engineering
  • Department of Electrical and Computer Engineering
Research Area 2차원 반도체 소자 및 재료, High-Performance 2D Electronics, Low-Power 2D Electronics, 뉴로모픽 소자 및 응용기술, 저전력 소자 및 소자물리

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