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Synthesis and Characterization of CIT-13, a Germanosilicate Molecular Sieve with Extra-Large Pore Openings
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kang, Jong Hun | - |
dc.contributor.author | Xie, Dan | - |
dc.contributor.author | Zones, Stacey I. | - |
dc.contributor.author | Smeets, Stef | - |
dc.contributor.author | McCusker, Lynne B. | - |
dc.contributor.author | Davis, Mark E. | - |
dc.date.accessioned | 2024-05-20T00:41:06Z | - |
dc.date.available | 2024-05-20T00:41:06Z | - |
dc.date.created | 2024-05-16 | - |
dc.date.issued | 2016-09 | - |
dc.identifier.citation | CHEMISTRY OF MATERIALS, Vol.28 No.17, pp.6250-6259 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.uri | https://hdl.handle.net/10371/203382 | - |
dc.description.abstract | The synthesis of the germanosilicate CIT-13, a molecular sieve that is the first to have a two-dimensional (2D) pore system possessing pores that are bounded by 14- and 10-rings, is accomplished using a family of monoquaternary, benzyl-imidazolium organic structure-directing agents (OSDAs) in aqueous media containing fluoride. CIT-13 is prepared using either hydrogen fluoride (HF) or ammonium fluoride (NH4F). The structure refinement suggests that most of the Ge atoms are located in the d4r(double-4-rings) units, and that there are framework disorders in the arrangement of those d4r units. Other characterizations of CIT-13 such as Si-29 MAS NMR spectra, Ar-adsorption isotherms, and so forth are presented and compared to those of IM-12 (UTL), a previously reported germanosilicate with 14- and 12-ring pores. | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Synthesis and Characterization of CIT-13, a Germanosilicate Molecular Sieve with Extra-Large Pore Openings | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.chemmater.6b02468 | - |
dc.citation.journaltitle | CHEMISTRY OF MATERIALS | - |
dc.identifier.wosid | 000383318500029 | - |
dc.identifier.scopusid | 2-s2.0-84987618963 | - |
dc.citation.endpage | 6259 | - |
dc.citation.number | 17 | - |
dc.citation.startpage | 6250 | - |
dc.citation.volume | 28 | - |
dc.description.isOpenAccess | Y | - |
dc.contributor.affiliatedAuthor | Kang, Jong Hun | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | POWDER DIFFRACTION | - |
dc.subject.keywordPlus | FRAMEWORK DENSITY | - |
dc.subject.keywordPlus | ZEOLITE | - |
dc.subject.keywordPlus | CHANNELS | - |
dc.subject.keywordPlus | RINGS | - |
dc.subject.keywordPlus | UNITS | - |
dc.subject.keywordPlus | GE | - |
dc.subject.keywordPlus | STABILIZATION | - |
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