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Synthesis and Characterization of CIT-13, a Germanosilicate Molecular Sieve with Extra-Large Pore Openings

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dc.contributor.authorKang, Jong Hun-
dc.contributor.authorXie, Dan-
dc.contributor.authorZones, Stacey I.-
dc.contributor.authorSmeets, Stef-
dc.contributor.authorMcCusker, Lynne B.-
dc.contributor.authorDavis, Mark E.-
dc.date.accessioned2024-05-20T00:41:06Z-
dc.date.available2024-05-20T00:41:06Z-
dc.date.created2024-05-16-
dc.date.issued2016-09-
dc.identifier.citationCHEMISTRY OF MATERIALS, Vol.28 No.17, pp.6250-6259-
dc.identifier.issn0897-4756-
dc.identifier.urihttps://hdl.handle.net/10371/203382-
dc.description.abstractThe synthesis of the germanosilicate CIT-13, a molecular sieve that is the first to have a two-dimensional (2D) pore system possessing pores that are bounded by 14- and 10-rings, is accomplished using a family of monoquaternary, benzyl-imidazolium organic structure-directing agents (OSDAs) in aqueous media containing fluoride. CIT-13 is prepared using either hydrogen fluoride (HF) or ammonium fluoride (NH4F). The structure refinement suggests that most of the Ge atoms are located in the d4r(double-4-rings) units, and that there are framework disorders in the arrangement of those d4r units. Other characterizations of CIT-13 such as Si-29 MAS NMR spectra, Ar-adsorption isotherms, and so forth are presented and compared to those of IM-12 (UTL), a previously reported germanosilicate with 14- and 12-ring pores.-
dc.language영어-
dc.publisherAMER CHEMICAL SOC-
dc.titleSynthesis and Characterization of CIT-13, a Germanosilicate Molecular Sieve with Extra-Large Pore Openings-
dc.typeArticle-
dc.identifier.doi10.1021/acs.chemmater.6b02468-
dc.citation.journaltitleCHEMISTRY OF MATERIALS-
dc.identifier.wosid000383318500029-
dc.identifier.scopusid2-s2.0-84987618963-
dc.citation.endpage6259-
dc.citation.number17-
dc.citation.startpage6250-
dc.citation.volume28-
dc.description.isOpenAccessY-
dc.contributor.affiliatedAuthorKang, Jong Hun-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.subject.keywordPlusPOWDER DIFFRACTION-
dc.subject.keywordPlusFRAMEWORK DENSITY-
dc.subject.keywordPlusZEOLITE-
dc.subject.keywordPlusCHANNELS-
dc.subject.keywordPlusRINGS-
dc.subject.keywordPlusUNITS-
dc.subject.keywordPlusGE-
dc.subject.keywordPlusSTABILIZATION-
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