Boosting electrochemical stability of ultralow-Pt nanoparticle with Matryoshka-like structure in polymer electrolyte membrane fuel cells

Abstract

Electrochemical catalysts with a core-shell structure have received much attention because of their enhanced efficiency and activity. Among them, those with a CuPd alloy core exhibit better activity than the ones with a single metal Pd core, which is known to be an excellent core-material. However, the superior performance of previously reported Pt catalysts with CuPd core has only been observed in half-cells, and was not reflected or even expanded to single-cells. We report catalysts having a Matryoshka-like structure with a Pt outer-layer, Cu interlayer, and Pd core for oxygen reduction reaction. This catalyst has 14 times higher Pt mass activity than the commercial PVC in half-cells, and also performs better in single-cells at only 0.056 mgp t cm(-2). Particularly, the stability of this catalyst satisfies the 2020 DOE target, and electrochemical surface area loss during the stability test is only 40 % for this catalyst, while that of Pt/C is 80 %.